Open Access

表2

HF-I的简化裂解反应模型

Reaction Ar/[(m3·mol-1)n-1·s] b Er/(kJ·mol-1)
C11.85H23.82→0.108 6H2+ 0.477 3CH4+0.558 6C2H4+ 0.39C2H6+0.41C3H6+ 0.200 1C3H8+0.224 6C4H8+ 0.035 3C4H10+0.031C4H6+ 0.485 7C5++0.511 2cC5++ 0.022 2C9H12 2.87×1014 0 217.9
C5+→0.14H2+0.48CH4+ 0.39C2H4+0.45C2H6+ 0.055C3H6+0.355C4H8+ 0.095 5C4H10+0.035 5C4H6+ 0.109 1C9H12 1.23×1012 0 189.6
cC5+→0.748 8C6H6+ 0.139 6C7H8+0.050 4C8H10+ 0.034 0C8H8+0.042 6C9H12 9.69×1012 0 194.4

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